On-board desulfurization is essential to operate fuel-cell-based auxiliary power units (APU) with commercial fuels. In this work, both (i) on-board desulfurization and (ii) on-board regeneration performance of Ag-Al₂O₃ adsorbent is investigated in a comprehensive manner. The herein investigated regeneration strategy uses hot APU off-gas as the regeneration medium and requires no additional reagents, tanks, nor heat exchangers and thus has remarkable advantages in comparison to state-of-the-art regeneration strategies. The results for (i) show high desulfurization performance of Ag-Al₂O₃ under all relevant operating conditions and specify the influence of individual operation parameters and the combination of them, which have not yet been quantified. The system integrated regeneration strategy (ii) shows excellent regeneration performance recovering 100% of the initial adsorption capacity for all investigated types of fuels and sulfur heterocycles. Even the adsorption capacity of the most challenging dibenzothiophene in terms of regeneration is restored to 100% over 14 cycles of operation. Subsequent material analyses proved the thermal and chemical stability of all relevant adsorption sites under APU off-gas conditions. To the best of our knowledge, this is the first time 100% regeneration after adsorption of dibenzothiophene is reported over 14 cycles of operation for thermal regeneration in oxidizing atmospheres.

Catalytic systems integrated in firewood stoves represent a potential secondary measure for emission reduction. However, the evaluation of catalytic efficiency is challenging since measurements, especially for PM emissions, upstream an integrated catalyst are not possible. Therefore, a special test facility, called “DemoCat”, was constructed which enabled parallel measurements in catalytically treated and untreated flue gas. The catalytic efficiency for CO, OGC and PM emissions was investigated under real-life operating conditions including ignition and preheating. The results confirmed a significant emission reduction potential (CO: > 95%, OGC: > 60%, PM: ∼30%). The conversion rates of CO and OGC emissions correlated with the space velocity and the coated area of honeycomb carriers which represent key parameters for the integration design. A quick response of the catalytic effect of around 5–12 min after ignition was observed when reaching 250 °C flue gas temperature at the catalyst. Most effective CO and OGC emission conversion was evident during the start-up and burn-out phase of a firewood batch. This reveals an important synergy for primary optimization which focuses particularly on the stretched intermediate phase of a combustion batch. The catalytic effect on PM emissions, especially on chemical composition, needs further investigations.

Dieser Bericht bietet eine ERhebung dero CO2e-Einsparungskosten außerhalb des ETS-Handels für den Bereich der Mobilität sowie der Wärmebereitstellung im häuslichen Sektor und Fern- und Nahwärme.

Several methods for identifying the phenomena of self-heating and off-gassing during production, transportation and storage of wood pellets have been developed in recent years. Research focused on the exploration of the underlying mechanisms, influencing factors or the quantification of self-heating or off-gassing tendencies. The present study aims at identifying a clear correlation between self-heating and off-gassing. Thus, different methods for determining self-heating and off-gassing potentials of wood pellets are compared. Therefore, eleven wood pellet batches from the European market were analyzed. For this investigation, three methods for the determination of self-heating, like isothermal calorimetry, oxi-press and thermogravimetric analysis, and four methods for off-gassing, like volatile organic compound (VOC) emissions measurements, gas phase analysis of stored pellets in a closed container by offline and by glass flask method and determination of fatty and resin acids content, were performed. Results were ranked according to the self-heating and off-gassing tendency providing a common overview of the analyzed pellets batches. Relations between different methods were investigated by Spearman’s correlation coefficient. Evaluation of the results revealed an equal suitability of offline and glass flask methods to predict off-gassing tendency and indicated a very significant correlation with isothermal calorimetry for the identification of self-heating tendency. The thermogravimetric analysis as well as the fatty and resin acids determination proved to be insufficient for the exclusive assessment of self-heating and off-gassing tendency, respectively.

The worldwide production of hydrogen in 2010 was estimated to be approximately 50 Mt/a, mostly based on fossil fuels. By using lignocellulosic feedstock, an environmentally friendly hydrogen production route can be established. A flow sheet simulation for a biomass based hydrogen production plant was published in a previous work. The plant layout consisted of a dual fluidized bed gasifier including a gas cooler and a dust filter. Subsequently, a water gas shift plant was installed to enhance the hydrogen yield and a biodiesel scrubber was used to remove tars and water from the syngas. CO2 was removed and the gas was compressed to separate hydrogen in a pressure swing adsorption. A steam reformer was used to reform the hydrocarbon-rich tail gas of the pressure swing adsorption and increase the hydrogen yield. Based on this work, a research facility was erected and the results were validated. These results were used to upscale the research plant to a 10 MW fuel feed scale. A validation of the system showed a chemical efficiency of the system of 60% and an overall efficiency of 55%, which indicates the high potential of this technology

There is a need to reduce NO_x emissions, which can only be achieved through a detailed understanding of the mechanisms for their formation and reduction. In this work the release of the NO_x precursors, NH₃ and HCN, for different fuels is experimentally analysed and modelled in typical fixed-bed combustion conditions. It is shown that NH₃ and HCN are released during the main devolatilization phase and the NH₃/HCN ratio increases for fuels with a higher nitrogen content. A simplified two-steps model for their release is presented. The model can predict with a reasonable accuracy the release for fuels with a low nitrogen content, however deviations are present for fuels with a high nitrogen content, which probably arise due to a reduction of NH₃ and HCN taking place already in the bed.

Dual fluidized bed biomass steam gasification generates a high calorific, practically nitrogen-free product gas with a volumetric H₂ content of about 40%. Therefore, this could be a promising route for a polygeneration concept aiming at the production of valuable gases (for example H₂), electricity, and heat. In this paper, a lab-scale process chain, based on state of the art unit operations, which processed a tar-rich product gas from a commercial dual fluidized bed biomass steam gasification plant, is investigated regarding H₂ production within a polygeneration concept. The lab-scale process chain employed a water gas shift step, two gas scrubbing steps, and a pressure swing adsorption step. During the investigations, a volumetric H₂ concentration of 99.9% with a specific H₂ production of 30 g kg⁻¹ biomass was reached. In addition, a valuable off-gas stream with a lower heating value of 7.9 MJ m⁻³ was produced. Moreover, a techno-economic assessment shows the economic feasibility of such a polygeneration concept, if certain feed in tariffs for renewable electricity and H₂ exist. Consequently, these results show, that the dual fluidized bed biomass steam gasification technology is a promising route for a polygeneration concept, which aims at the production of H₂, electricity, and district heat.

This study describes a modified process of ammonia release through pre-hydrolysis – ammonia removal via membrane contactor – methanization for counteracting ammonia inhibition in anaerobic digestion of chicken manure. In the pre-hydrolysis step, ammonia was rapidly released within the first 3–5 days. 78%-83% of the total nitrogen was finally converted into total ammonia/ammonium (TAN) with volatile fatty acids concentration of approximately 300 g/kg·VS. In the ammonia removal process, diluting the hydrolyzed chicken manure to 1:2, the TAN could be reduced to 2 g/kg in 21 h when pH was increased to 9. The final BMP test of chicken manure verified that lower TAN concentration (decreased to 2 g/kg) significantly reduced inhibitory effects, obtaining a high methane yield of 437.0 mL/g·VS. The investigations underlined several advantages of this modified process.

A cold flow model of an 8 MW dual fluidized bed (DFB) system is simulated using the commercial computational particle fluid dynamics (CPFD) software package Barracuda. The DFB system comprises a bubbling bed connected to a fast fluidized bed with the bed material circulating between them. As the hydrodynamics in hot DFB plants are complex because of high temperatures and many chemical reaction processes, cold flow models are used. Performing numerical simulations of cold flows enables a focus on the hydrodynamics as the chemistry and heat and mass transfer processes can be put aside. The drag law has a major influence on the hydrodynamics, and therefore its influence on pressure, particle distribution, and bed material recirculation rate is calculated using Barracuda and its results are compared with experimental results. The drag laws used were energy-minimization multiscale (EMMS), Ganser, Turton–Levenspiel, and a combination of Wen–Yu/Ergun. Eleven operating points were chosen for that study and each was calculated with the aforementioned drag laws. The EMMS drag law best predicted the pressure and distribution of the bed material in the different parts of the DFB system. For predicting the bed material recirculation rate, the Ganser drag law showed the best results. However, the drag laws often were not able to predict the experimentally found trends of the bed material recirculation rate. Indeed, the drag law significantly influences the hydrodynamic outcomes in a DFB system and must be chosen carefully to obtain meaningful simulation results. More research may enable recommendations as to which drag law is useful in simulations of a DFB system with CPFD.

Scheitholzkessel sind die in Europa immer noch am stärksten verbreitete Form von Holz-basierten Zentralheizungssystemen. Der Bestand ist überaltert und weist die größten Anteile an den verursachten Schadstoffemissionen aus Festbrennstoffzentralheizungssystemen auf. Das Ziel des Projektes, die komplette Neuentwicklung einer modellbasierten Regelung für Scheitholzkessel mit Pufferspeichern und einer Solaranlage, stellte einen Technologie-sprung in Richtung einer drastischen Reduktion der Schadstoffemissionen (CO, org. C, Fein-staub) bei gleichzeitiger Erhöhung des Nutzungsgrades und Benutzerkomforts dar. Dabei erfolgte sowohl die übergeordnete Regelung des Zusammenspiels der Komponenten (Systemregelung) als auch die Regelung der einzelnen Komponenten (Feuerungsregelung, Hydraulikregelung) modellbasiert. Die neue Regelung basiert auf einer gezielten Interaktion mit dem Benutzer, in welcher der Benutzer zielgerichtet zum Nachlegen einer bestimmten Brennstoffmenge in einem bestimmten Zeitraum aufgefordert wird. Zusätzlich dazu werden alle Teilprozesse (Verbrennung des Scheitholzes, Übertragung der Wärme in den Pufferspeicher, usw.) modellbasiert und damit deutlich effizienter und genauer geregelt. Im Fall der Feuerungsregelung wurde zusätzlich zur modellbasierten Regelung von Vorlauf-temperatur und Sauerstoffgehalt auch eine innovative CO-l-Regelung eingesetzt, die basierend auf einer kontinuierlichen Schätzung der CO- l-Charakteristik unter Verwendung eines kombinierten Sensors zur Sauerstoffmessung und Detektion unverbrannter Kompo-nenten stets einen für den aktuellen Betriebszustand optimalen Sollwert für den Sauer-stoffgehalt vorgibt. Die laufende Anpassung des Sauerstoffgehaltes führt zu einer deutlichen Reduktion der Schadstoffemissionen (CO, org. C, Feinstaub). Zum Erreichen dieser Ziele wurden im Wesentlichen folgende Schritte durchgeführt:

• Experimentelle Untersuchung und Modellierung des Abbrandverhaltens von Scheitholz (inklusive der CO-l-Charakteristik)
• Entwicklung einer übergeordneten modellbasierten Systemregelung
• Entwicklung einer modellbasierten Feuerungsregelung (inkl. CO-l-Regelung) für einen effizienten und schadstoffarmen Betrieb des Scheitholkessels
• Experimentelle Bewertung des Potentials der modellbasierten Regelung
• Analyse der Anforderungen zur Anpassung der Regelung an andere Konfigurationen

Das beantragte Projekt leistete somit einen entscheidenden Beitrag zum Ausschreibungs-schwerpunkt „Effiziente und emissionsarme Klein- und Kleinstfeuerungen durch Integration einer intelligenten Verbrennungs- und Leistungsregelung“ und ging zusätzlich explizit auf die im Ausschreibungsleitfaden adressierte Verwendung von kombinierten Sensorsystemen wie CO- l-Sensorsysteme zur Verbrennungsregelung ein. Dabei ist insbesondere hervorzuheben, dass der durchdachte Ansatz das Sensorsignal zu Schätzung der CO- l-Charakteristik zu verwenden den wesentlichen Vorteil mit sich bringt, dass die exakte Messung der CO-Emissionen durch den Sensor nicht erforderlich ist, sondern es ausreicht, wenn dieser die Tendenzen richtig wiedergibt.

We briefly review the general concept and expected market potential of microgrids, then discuss the
optimization challenges associated with planning local cross-sectorial energy systems. A fair technology-
neutral approach to this optimization task leads to a hard problem, which has to be tackled with
advanced methods of mathematical optimization.
The power of this approach is illustrated in a case study, concerning the replacement of heating systems
in an alpine valley. In this case study we see both the potential for cost reduction and for the reduction
of CO2 emissions by an integrated planning approach